Ferroelectricity: It is a characteristic of certain materials that have a spontaneous electric polarization that can be reversed by the application of an external electric field.
Magneto Ferroelectricity:
Magnetic spins interact with the lattice structure, leading to a coupling between magnetic and ferroelectric properties. Here the applied magnetic field causes the structural deformation of the material by changing the bond lengths and bond angles, which inevitably leads to the change of internal dipoles.
The magnetic interactions of transition metal ions with unpaired d electrons are generally sensitive to the deformation of bond lengths and angles.
(TMCM)[FeCl4] was studied here.
A second harmonic generation was conducted. It indicates change of noncentrosymmetric structure to a centrosymmetric. SHG signal changes sharply around 320K.
The local ferroelectric domains within (TMCM)[FeCl4] were calculated by piezoelectric force microscopy (PFM). Magnetostriction was measured by Atomic Force Microscopy. (Magnetostriction is the ability of a material to undergo mechanical strain in response to a magnetic field.)
The external magnetic field strongly affects the ferroelectric loops, leading to changes in their symmetry, amplitude, and coercive fields( Coercive field is the strength of a magnetic or electric field that's required to demagnetize or depolarize a material).
As per study, polarization along the a-axis is suppressed by the magnetic field,which corresponds to the stretching of the halogen Cl‧‧‧Cl bonds and the shrinking volume occupancy of [FeCl4]− anions.
The density functional theory (DFT) calculations were performed with projector-augmented wave pseudopotentials-a technique used in electronic structure calculations.
polarization was calculated using the standard Berry phase method. This helps to calculate valence electronic and ionic contribution.
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